Research Interest
Polymer Synthesis; Polymer Blends and Composites; Ionic Liquids; Membranes; Organic Porous Materials; CO2 Capture and Sequestration; Gas Separation; Carbon Molecular Sieves; Wastewater Treatment; Ultra-Nano Filtration; Oil/Water Separation; Conductivity; Li-Batteries; Fuel Cells
Dr. Irshad Kammakakam received his Ph.D. in Chemistry from Incheon National University, South Korea in 2015. Dr. Kammakakam joined Nazarbayev University in the fall of 2023 as an Assistant Professor of Chemistry. His research focused on developing advanced organic porous materials and functional polymeric membranes for energy-saving separation technology and environmental green energy applications. Before joining Nazarbayev University, Dr. Kammakakam was a Research Scientist at the Advanced Materials Chemistry Center, Khalifa University, UAE. He also worked as a Visiting Scientist at the Korea Institute of Science and Technology, South Korea (March 2015 to November 2016) and completed multiple Postdocs at the European Institute of Membranes, France (June 2017 to May 2018), the University of Alabama, USA (May 2018 to August 2021), and the King Abdullah University of Science and Technology, Saudi Arabia (August 2021 to November 2022). Dr. Kammakakam has bagged many awards and achievements including the recipient of the 2020 Future Faculty Mentoring Program sponsored by the EdDiv of the American Institute of Chemical Engineers (AIChE). He also serves as an academic editor as well as a reviewer in several high-impact factor Q1 journals, including Polymers, Membranes, and Frontiers in Environmental Chemistry.
Dr. Kammakakam’s group has mainly focused on the design, synthesis, and characterization of functional polymers and organic porous materials for applications in gas/liquid separation, CO2 capture, oil/water separation, wastewater treatments, and energy conversion and storage. He has recently invented novel Ionene polymers as unprecedented CO2 sequestration membranes with Prof. Jason E. Bara at the University of Alabama, USA. Dr. Kammakakam has developed the very first anionic Poly(IL) systems for gas separation technology and successively completed two main projects for the Department of Energy and NASA on “Design and Synthesis of Ionic-polymers for Gas separation Membranes as well as Shape-memory and Self-healing applications”. Dr. Kammakakam is highly skilled in designing of porous polymer materials to utilize as Ultrafiltration membranes for Oil/Water separation. In his recent studies, various advanced polymers and porous materials have been developed for wastewater treatment and ion separation technologies. Furthermore, novel pendant, as well as backbone tethered imidazolium functionalized mono/dual cationic groups having OH– anions on Poly(ether ketone)s and Poly(ether sulfone)s, are focused as polymer
electrolytes for alkaline exchange fuel cell (AEMFC) applications.
- Irshad Kammakakam* and Zhiping Lai. “Next-Generation Ultrafiltration Membranes: A Critical Review of Material Design, Properties, Progresses, and Challenges”. Chemosphere 2023, 316, 137669 (Impact Factor: 8.943).
- Nadeem Baig and Irshad Kammakakam*. Special wettable Azadirachta indica leaves like microarchitecture mesh membrane for layered oil/water separation. Chemosphere 2023, 313, 137544 (Impact Factor: 8.943)
- Irshad Kammakakam, Kathryn O’Harra, Jason E. Bara, and Enrique M. Jackson. Spirobisindane-Containing Imidazolium Polyimide-Ionene: Structural Design and Gas Separation Performance of “Ionic PIMs”. Macromolecules 2022, 55, 4790−4802 (Impact Factor: 6)
- Kathryn O’Harra, Irshad Kammakakam, Tuan Yi, Enrique M. Jackson, and Jason E. Bara. “PEEK-Ionenes: Ultra High-Performance Polymers Meet Ionic Liquids”. ACS Appl. Polym. Mater. 2022, 4, 8365-8376 (Impact Factor: 4.855)
- Nadeem Baig, Abdulaziz Mohammed Alowaid, Ismail Abdulazeez, Billel Salhi, and Irshad Kammakakam*. Designing of nanotextured antifouling inorganic-organic hybrid PVDF membrane for efficient separation of the oil-in-water emulsions. Chemosphere 2022, 308, 136531 (Impact Factor: 8.943)
- Smitha S Patil, V Madhura, Irshad Kammakakam, MH Halashankar Swamy, K Sadashiva Patil, Zhiping Lai, Anil Rao HN. Quinuclidinium-piperidinium based Dual Hydroxide Anion Exchange Membranes as Highly Conductive and Stable Electrolyte Materials for Alkaline Fuel Cell Applications. Electrochim. Acta 2022, 426, 140826 (Impact Factor: 7.336)
- Chandan Giri, Sarah E Sisk, Louis Reisman, Irshad Kammakakam, Jason E Bara, Kevin N West, Brooks D Rabideau, and Paul A Rupar. Anionic Ring-Opening Polymerizations of N-Sulfonylaziridines in Ionic Liquids. Macromolecules, 2022, 55, 2, 623–629 (Impact Factor: 6).
- Irshad Kammakakam, Kathryn O’Harra, Jason E. Bara, and Enrique M. Jackson. Synthesis of Imidazolium-Mediated Poly(benzoxazole) Ionene and Composites with Ionic Liquids as Advanced Gas Separation Membranes. Polymer, 2021, 214, 123239 (Impact Factor: 4.43).
- Nadeem Baig* and Irshad Kammakakam*. “Removal of oily contaminants from water by using the hydrophobic nanoparticle incorporated dopamine modified cellulose foam”. Polymers, MDPI, 2021, 13(18), 3163 (Impact Factor: 4.967).
- Nadeem Baig, Irshad Kammakakam* and W. S. Falath. Nanomaterials: A review of synthesis, properties, recent progress, and challenges. Mater. Adv., 2021, 2, 1821-1871. Cover of the Issue.
- Irshad Kammakakam, Jason E. Bara and Enrique M. Jackson. Dual Anionic-Cationic Crosslinked Poly(ionic liquid) Composite Membranes for Enhanced CO2 Separation. ACS Appl. Polym. Mater. 2020, 2, (11), 5067–5076 (Impact Factor: 4.855). Highlighted Article in ASAP Publications
- Irshad Kammakakam, Jason E. Bara and Enrique M. Jackson. Synthesis and Characterization of Imidazolium-Mediated Tröger’s Base Containing Poly(amide)-Ionenes and Their Ionic Liquid Composites for CO2 Separation Membranes. Polym. Chem., 2020, 11, 7370-7381 (Impact Factor: 5.364).
- Irshad Kammakakam, Jason E. Bara, Enrique M. Jackson, Josu Lertuxundi, David Mecerreyes and Liliana C. Tome. Tailored CO2-philic Anionic Poly(ionic liquid)s Composite Membranes: Synthesis, Characterization, and Gas Transport Properties. ACS Sustain. Chem. Eng. 2020, 8 (15), 5954-5965 (Impact Factor: 9.224). Highlighted Article in ASAP Publications
- Shuai Qian, Xiaoyang Liu, Vladimir N. Emel’yanenko, Patryk Sikorski, Irshad Kammakakam, Brian S. Flowers, Tristin A. Jones, Heath C. Turner, Sergey P. Verevkin and Jason E. Bara. Synthesis and Properties of 1,2,3-Triethoxypropane: A Glycerol-Derived Green Solvent Candidate. Ind. Eng. Chem. Res.2020, 59 (45) 20190–20200 (Impact Factor: 4.326).
- Milad R. Esfahani, Autumn Taylor, Zane J. Parkerson, Nicole Serwinowski, Amirsalar R. Esfahani, Irshad Kammakakam, Jason E. Bara, S. Nima Mahmoodi and Michael Z. Hu. Sustainable Novel Bamboo-Based Membranes for Water Treatment Fabricated by Regeneration of Bamboo Waste Fibers. ACS Sustain. Chem. Eng. 2020, 8 (10), 4225-4235 (Impact Factor: 9.224).
- Patrick G. Dennis, Kathryn O’Harra, Irshad Kammakakam, Tristin A. Jones, Enrique M. Jackson, and Jason E. Bara. 6FDA‐containing polyimide‐ionene+ ionic liquid gas separation membranes. J Polym. Sci. 2020, 58 (18), 2664-2674.
- Kathryn O’Harra, Irshad Kammakakam, Danielle M. Noll, Erika M. Turflinger, Grayson P. Dennis, Enrique M. Jackson, and Jason E. Bara. Synthesis and Performance of Aromatic Polyamide Ionenes as Gas Separation Membranes. Membranes 2020, 10(3), 51 (Impact Factor: 4.562).
- Kathryn O’Harra, Danielle M. Noll, Irshad Kammakakam, Emily M. DeVriese, Gala Solis, Enrique M. Jackson, and Jason E. Bara. Synthesis and Characterization of Amide-linked Ionenes for Advanced Applications. Polymers 2020, 12(6), 1254 (Impact Factor: 4.967).
- Irshad Kammakakam, Kathryn O’Harra, Jason E. Bara, and Enrique M. Jackson. Design and Synthesis of Imidazolium-Mediated Tröger’s Base-containing Ionene Polymers for Advanced CO2 Separation Membranes. ACS Omega 2019, 4 (2), 3439–3448 (Impact Factor: 4.132).
- Irshad Kammakakam, Kathryn O’Harra, Patrick G. Dennis, Enrique M. Jackson, and Jason E. Bara. Self-Healing Imidazolium-based Ionene-Polyamide Membranes: An Experimental Study on Physical and Gas Transport Properties. Polym Int. 2019, 68, 1123-1129. (Impact Factor: 3.213) Top downloaded paper 2018-2019.
- Kathryn O’Harra, Irshad Kammakakam, Enrique M. Jackson, and Jason E. Bara. Understanding the Effects of Backbone Chemistry and Anion Type on the Structure and Thermal Behaviors of Imidazolium Polyimide-Ionenes. Polym Int. 2019, 68, 1547-1556. (Impact Factor: 3.213)
- Kathryn O’Harra, Irshad Kammakakam, Emily M. Devriese, Danielle M. Noll, Jason E. Bara, and Enrique M. Jackson. Synthesis and Performance of 6FDA-Based Polyimide-Ionenes and Composites with Ionic Liquids as Gas Separation Membranes. Membranes 2019, 9(7), 79 (Impact Factor: 4.562).
- Irshad Kammakakam1, An He Seong,1 Albert Sung Soo Lee,1 Seungsang Hwang, and Jong-Suk Lee. Bromination/Debromination-Induced Thermal Crosslinking of 6FDA-durene for Aggressive Gas Separation. J. Membr. Sci. 2018, 545, 358-366. (Impact Factor: 10.53) 1The authors contributed equally to this work.
- Bumjin Gye, Irshad Kammakakam, Hyelim You, SangYong Nam, and Tae-Hyun Kim. PEG-Imidazolium-Incorporated Polyimides as High-Performance CO2-selective Polymer Membranes: The Effects of PEG-Imidazolium Content. Sep. Purif. Technol. 2017, 179, 283–290. (Impact Factor: 9.136)
- Irshad Kammakakam, SangYong Nam, and Tae-Hyun Kim. PEG-Imidazolium-Functionalized 6FDA-Durene Polyimide as a Novel Polymeric Membrane for Enhanced CO2 Separation. RSC Adv. 2016, 6, 31083-31091. (Impact Factor: 4.036)
- Irshad Kammakakam, SangYong Nam and Tae-Hyun Kim. Ionic Group-Mediated Crosslinked Polyimide Membranes for Enhanced CO2 Separation. RSC Adv. 2015, 5, 69907-69914. (Impact Factor: 4.036)
- Irshad Kammakakam, Hee Wook Yoon, SangYong Nam, Ho Bum Park, and Tae-Hyun Kim. Novel Piperazinium-Mediated Crosslinked Polyimide Membranes for High-Performance CO2 Separation. J. Membr. Sci. 2015, 487, 90-98. (Impact Factor: 10.53)
- Irshad Kammakakam, Hee Wook Yoon, SangYong Nam, Ho Bum Park, and Tae-Hyun Kim. An Imidazolium-based Ionene Blended into Crosslinked PEO as a Novel Polymer Membrane for Selective CO2 Separation. Macromol. Res. 2014, 22, 907-916. (Impact Factor: 2.127)
- Irshad Kammakakam, Hyo Won Kim, SangYong Nam, Ho Bum Park, and Tae-Hyun Kim. Alkyl Imidazolium-Functionalized Cardo-based Poly(ether ketone)s as Novel Polymer Membranes for O2/N2 and CO2/N2 Separations. Polymer 2013, 54, 3534-3541. (Impact Factor: 4.43)
- Abhishek Dutta Chowdhury, Amit Das, Irshad Kammakakam, Shaikh M. Mobin, and Goutam Kumar Lahiri. Isomeric Complexes of [RuII(trpy)(L)Cl] (trpy = 2,2′:6′,2′′-Terpyridine and HL = Quinaldic Acid): Preference of Isomeric Structural Form in Catalytic Chemoselective Epoxidation Process. Inorg. Chem. 2011, 50, 1775–1785. (Impact Factor: 5.436)
Spring 2023
- CHEM 212 – Organic Chemistry II
- CHEM 212L – Organic Chemistry II Lab