Research Interest
Computational design, synthesis, and fabrication of organic/hybrid solar cells (dye-sensitized, polymer, and perovskites);
Design and synthesis of functional materials for energy, environmental and biomedical applications; and
Environmental analysis and monitoring.
BIOGRAPHY
Dr. Mannix P. Balanay earned his Ph.D. in physical chemistry from Kunsan National University in the Republic of Korea in 2012, where he studied the design, synthesis and fabrication of dye-sensitized solar cells. During his Ph.D. studies, he learned various density functional theory methods for the theoretical design of dyes and polymers used in organic solar cells. He was also trained in the organic synthesis of the dyes and their processing into solar cells. After completing his PhD, he was eventually hired as a research professor at the same university, where he continued his research on third-generation solar cells. Before coming to Korea, he was a lecturer at Siquijor State College and Silliman University. He holds two master’s degrees in chemistry with specialization in computational chemistry (from Kunsan National University) and bioinorganic chemistry (from Mindanao State University – Iligan Institute of Technology, Republic of the Philippines). During his time in the Philippines, he has done a lot of work in environmental research, starting with his undergraduate thesis sponsored by the Philippine National Oil Company, where he studied the impact of the plant’s exhaust on rain quality in the region. At Siquijor State College, he was not only a lecturer but also a scientific research specialist in coastal resource management, where he learned underwater diving and earned his license as an advanced open water diver. At Silliman University, he was the Chemist of the Chemistry Department’s Commercial Analysis Laboratory, where he performed various chemical analyzes, primarily of soil and water, for different sectors of the community. His specialization in bioinorganic chemistry allowed him to gain experience with bacterial cell culture and protein profiling. In 2014, he was appointed Assistant Professor at the Department of Chemistry of Nazarbayev University and promoted to Associate Professor in 2020. Previously, he was a member of the Scientific and Technical Council of the Center for Energy and Advanced Materials of the National Laboratory of Astana.
In 2019, he was awarded the “Balik (returning) Scientist Program” award of the Philippine Council for Industry, Energy, and Emerging Technology Research and Development of the Department of Science and Technology (DOST-PCIEERD) of the Republic of the Philippines in coordination with the Chemistry Department of the Mindanao State University – Iligan Institute of Technology. He is currently a technical panel member for nanomaterials for the DOST-PCIEERD.
RESEARCH INTERESTS
Dr. Balanay applies a comprehensive approach to study a range of functional materials critical to society’s pressing needs, including energy, environment, and health. His research spans multiple disciplines of chemistry and includes computational chemistry, materials chemistry, environmental chemistry, organic chemistry, and inorganic chemistry. Currently, his research focuses on the following key areas: (a) Computational design, synthesis, and fabrication of organic/hybrid solar cells, with particular emphasis on dye-sensitized, polymer, and perovskite solar cells. Using advanced computational methods, Dr. Balanay aims to optimize the design and manufacturing processes of these solar cells to achieve higher efficiency and performance. (b) Synthesis of nanomaterials tailored for energy, environmental, and biomedical applications. Dr. Balanay is actively engaged in the synthesis of nanomaterials with specific properties to address challenges in areas such as energy generation, environmental remediation/catalysis, and biomedical advances. And (c) environmental analysis and monitoring. Dr. Balanay is developing environmental sensors to assess and monitor the impact of various substances on the environment. By developing novel analytical methods, he hopes to contribute to a better understanding of environmental pollutants and their potential impact on ecosystems and human health.
Through his diverse research interests and expertise, Dr. Balanay is committed to advancing research in functional materials and meeting societal needs in the areas of energy, environment and health.
For information on his research lab and grants, please click on this link.
- E.K. Adotey, M.P. Balanay, D. Shah, P.K. Hopke, S. Sabanov, M. Amouie Torkmahalleh. Heterogeneous (gas-solid) chemistry of atmospheric Cr: A case study of Astana, Kazakhstan. Environ. Pollut. 344 (2024) 123210.
- E.K. Adotey, M. Amouie Torkmahalleh, L. Tastanova, A. Bekeshev, D. Shah, P.K. Hopke, W. Lee. M.P.Balanay. Ultrasensitive fluorescent carbon dot sensor for quantification of soluble and insoluble Cr(VI) in particulate matter. J. Hazard. Mater. 462 (2024) 132671.
- D. Aidarkhanov, Z. Yelzhanova, Z. Ren, G. Nigmetova, S.P. Lau, M.P. Balanay, H. Hu, C. Surya, A.B. Djurišić, A. Ng. Synergic effects of incorporating black phosphorus for interfacial engineering in perovskite solar cells. Surf. Interfaces 43 (2023) 103531.
- Y. Tashenov, D. Suleimenova, B. Baptayev, S. Adilov, M.P. Balanay. Efficient one-step synthesis of a Pt-Free Zn0.76Co0.24S counter electrode for dye-sensitized solar cells and its versatile application in photoelectrochromic devices. Nanomaterials 13 (2023) 2812.
- D. Suleimenova, Y. Tashenov, M.P. Balanay, B. Baptayev. Unveiling the potential of MnxCo3-xS4 electrocatalyst in triiodide reduction for dye-sensitized solar cells. Bull. Karaganda Univ.-Phys. 3 (2023) 58-64.
- A. Valeriano, F. Bondaug, I. Ebardo, P. Almonte, M.A. Sabugaa, J.R. Bagnol, M.J. Latayada, J.M. Macalalag, B.D. Paradero, M. Mayes, M.P. Balanay, A. Alguno, R. Capangpangan. Predicting cytotoxicity of engineered nanoparticles using regularized regression models: An in silico approach. SAR QSAR Environ. Res. 34 (2023) 591.
- G. Nuroldayeva, M.P. Balanay. Flexing the spectrum: Advancements and prospects of flexible electrochromic materials. Polymers 15 (2023) 2924.
- B. Baptayev, Y. Tashenov. M.P. Balanay. Foam for Sensors. In R.K Gupta, Ed. Polymeric Foams: Applications of Polymeric Foams (Volume 2). American Chemical Society (2023) pp. 233-251.
- B. Baptayev, Y. Tashenov. M.P. Balanay. Metal oxide-based flexible and wearable sensors. In R.K Gupta, Ed. Flexible and wearable sensors: Materials, technologies, and challenges. CRC Press (2023) pp. 135-148.
- P.A. Barredo, M.P. Balanay. Recent advances in molecular dynamics simulations of tau fibrils and oligomers. Membranes 13 (2023) 277.
- B. Baptayev, Y. Tashenov, S. Adilov, M.P. Balanay. Facile fabrication of ZnCo2S4@MWCNT as Pt-free counter electrode for high performance dye-sensitized solar cells. Surf. Interfaces 37 (2023) 102699.
- E.K. Adotey, M. Amouie Torkmahalleh, P. Hopke, M.P. Balanay. N,Zn-doped fluorescence sensor based on carbon dots for subnanomolar detection of soluble Cr(VI) ions. Sensors 23 (2023) 1632.
- B. Baptayev, Y. Tashenov, A. Aliakbarova, S. Adilov, M.P. Balanay. Ternary NiCuS electrocatalyst for iodide/triiodide reduction in dye-sensitized solar cells. Mater. Today: Proc. 71 (2022) 94.
- B. Davlatiyarov, K. Akmurzina, A. Seralin, G. Bizhanova, B. Baptayev, M.P. Balanay, A. Ng. Investigation of synthesis and deposition methods for Cesium-based perovskite quantum dots for solar cell applications. Eurasian Chem.-Technol. J. 24 (2022) 241.
- E.K. Adotey, L. Burkutova, L. Tastanova, A. Bekeshev, M.P. Balanay, S. Sabanov, A.M. Rule, P.K. Hopke, M. Amouei Torkmahalleh. Quantification and the sources identification of total and insoluble hexavalent chromium in ambient PM: A case study of Aktobe, Kazakhstan. Chemosphere 307 (2022) 136057.
- B. Baptayev, S.-M. Kim, B. Bolatbek, S.H. Lee, M.P. Balanay. Effect of π-spacer length in novel xanthene-linked L-(D−π–A)2-type dianchoring dyes for dye-sensitized solar cells. ACS Appl. Energy Mater. 5 (2022) 6764.
- Z. Yelzhanova, G. Nigmetova, D. Aidarkhanov, B. Daniyar, B. Baptayev, M.P. Balanay, A.N. Jumabekov, A. Ng. A morphological study of solvothermally grown SnO2 nanostructures for application in Perovskite solar cells. Nanomaterials 12 (2022) 1686.
- B. Baptayev, Y. Tashenov, M.P. Balanay. Conjugated Polymers as Organic Electrodes for Photovoltaics. In R.K Gupta, Ed. Organic Electrodes: Fundamental to Advanced Emerging Applications, Engineering Materials. Springer, Cham. (2022) pp. 137-153.
- B. Baptayev, S.-M. Kim, B. Bolatbek, S.H. Lee, M.P. Balanay. The effect of coupling and di-anchoring group in the performance of triphenylamine-based dyes for dye-sensitized solar cells. Dyes Pigm. 198 (2022) 110020.
- P.A. Barredo, M.J.F. Fernandez, C.E. Ambe, M.P. Balanay. Tau fibril with membrane lipids: Insights from computational modeling and simulations. PLoS One 16 (2021) e0258692.
- B. Baptayev, D. Mustazheb, Z. Abilova, M.P. Balanay. Nanostructured flower-shaped CuCo2S4 as a Pt-free counter-electrode for dye-sensitized solar cells. Chem. Commun. 56 (2020) 12190.
- E.K. Adotey, M. Amouei Torkmahalleh, M.P. Balanay. Zinc metal-organic framework with 3-pyridinecarboxaldehyde and trimesic acid as co-ligands for selective detection of Cr(VI) ions in aqueous solution. Methods Appl. Fluoresc. 8 (2020) 045007.
- D. Aidarkhanov, Z. Ren, C.-K. Lim, Z. Yelzhanova, G. Nigmetova, G. Taltanova, B. Baptayev, F. Liu, S.H. Cheung, M.P. Balanay, A. Baumratov, A.B. Djursic, S.K. So, C. Surya, P.N. Prasad, A. Ng. Passivation engineering of hysteresis-free mixed perovskite solar cells. Sol. Energy Mater. Sol. Cells 215 (2020) 110648.
- B. Baptayev, S. Adilov, M.P. Balanay. Surface modification of TiO2 photoanodes with In3+ using a simple soaking technique for enhancing the efficiency of dye-sensitized solar cells. J. Photochem. Photobiol. A 394 (2020) 112468.
- B. Baptayev, D. Mustazheb, M.P. Balanay. Binary transition metal sulfides as an economical Pt-free counter electrodes for dye-sensitized solar cells. Mater. Today: Proc. 25 (2020) 24.
- B. Baptayev, A. Aukenova, D. Mustazheb, M. Kazaliyev, M.P. Balanay. Pt-free counter electrode based on orange fiber-derived carbon embedded cobalt sulfide nanoflakes for dye-sensitized solar cells. J. Photochem. Photobiol. A 383 (2019) 111977.
- B. Baptayev, S.H. Lee, D.H. Kim, M.P. Balanay. Controlling aggregation using self-assembled axially coordinated pyridine-based ligands on porphyrin analogues for dye-sensitized solar cells. Chem. Phys. Lett. 730 (2019) 407.
- R.J. O’Reilly, M.P. Balanay. A quantum chemical study of the effect of substituents in governing the strength of the S-F bonds of sulfenyl-type fluorides toward homolytic dissociation and fluorine atom transfer. Chem. Data Collect. 20 (2019) 100186.
- B. Baptayev, A. Rysbekova, D. Kalpakov, A. Aukenova, D. Mustazheb, Z. Salkenova, M. Kazaliyev, M.P. Balanay. Control of porphyrin dye aggregation using bis(4-pyridyl)alkanes in dye sensitized solar cells. Eurasian Chem.-Technol. J. 21 (2019) 63.
- R.J. O’Reilly, M.P. Balanay. Homolytic SCl Bond dissociation enthalpies of sulfenyl chlorides-a high level G4 thermochemical study. Chem. Data Collect. 19 (2019) 100180.
- K.A. Gudun, M. Segizbayev, A. Adamov, P.N. Plessow, K.A. Lyssenko, M.P. Balanay, A.Y. Khalimon. POCN Ni (II) complexes: synthesis, characterization and evaluation of catalytic hydrosilylation and hydroboration activities. Dalton Trans. 48 (2019) 1732.
- L. Bo, Y. Hy, Z. Zhang, M.P. Balanay, H. Fan, J. Tong. Highly efficient oxidation of cyclopentene catalyzed by magnetically recoverable Ca-Co ferrite spinels with high solvent selectivity. Polyhedron 154 (2018) 182-188.
- A.A. Nurkesh, M.P. Balanay, T. Yeleusizov, D. Tursynkhan, Q. Yang, X. Wan, L. Manarbek, A. Maipas, B. Matkarimov, Y. Zhang, H. Fan, L.-X. Miao, S.P. Li, Z. Chen, Y. Xie. Natural product-derived carbon nanodots overcome drug resistance through regulation of Hippo pathway effectors. Cancer Res. 78 (2018) 5498.
- L.L. Estrella, M.P. Balanay, D.H. Kim. Theoretical insights into D-D-p-A sensitizers employing N-annulated perlyne for dye-sensitized solar cells. J. Phys. Chem. A 122 (2018) 6328-6342.
- Y. Xie, Q. Sun, A. Nurkesh, J. Lu, S. Kauanova, J. Feng, D. Tursynkhan, Q. Yang, A. Kassymbek, M. Karibayev, K. Duisenova, H. Fan, X. Wang, L. Manarbek, A. Maipas, Z. Chen, M.P. Balanay. Dysregulation of YAP by ARF stimulated with tea-derived carbon nanodots. Sci. Rep. 7 (2017) 16577.
- H.M.T. Albuquerque, C.M.M. Santos, M.P. Balanay, J.A.S. Cavaleiro, A.M.S. Silva. 1,6-conjugate addition of carbon nucleophiles to 2-[(1E,3E)-4-arylbuta-1,3-dien-1-yl]-4H-chromen-4-ones. (2017) Eur. J. Org. Chem. 2017 (2017) 5293.
- M.P. Balanay, D.H. Kim. Strategic design of bacteriochlorins as possible dyes for photovoltaic applications. J. Phys. Chem. A 121 (2017) 6660.
- Y. Xie, O. Filchakova, Q. Yang, Y. Yesbolatov, D. Tursynkhan, A. Kassymbek, M. Bouhrara, K. Wang, M.P. Balanay, H. Fan. Inhibition of cancer cell proliferation by carbon-dots derived from date pits at low-dose. ChemistrySelect 2 (2017) 4079.
- M.A.B. Gapol, M.P. Balanay, D.H. Kim. Molecular engineering of tetraphenylbenzidine-based hole transport material for Perovskite solar cell. J. Phys. Chem. A 121 (2017) 1371.
- M.P. Balanay, K-S. Choi, S.H. Lee, D.H. Kim. Experimental and theoretical analysis of organic dyes having a double D-p-A configurations for dye-sensitized solar cells. Spectrochim. Acta, Part A 173 (2017) 361.
- L.L. Estrella, M.P. Balanay, D.H. Kim. The effect of donor group rigidification on the electronic and optical properties of arylamine-based metal-free dyes for dye-sensitized solar cells: A computational study. J. Phys. Chem. A 120 (2016) 5917.
- G. Ghana Kumar, M.P. Balanay, R. Nirmala, D.H. Kim, T. Raj Kumar, N. Senthi Kumar, A.R. Kim, D.J. Yoo. The photovoltaic performances of PVdF-HFP electrospun membranes employed quasi-solid state dye sensitized solar cells. J. Nanosci. Nanotech. 16 (2016) 581.
- M.P. Balanay, D.H. Kim, H. Fan. Revisiting the formation of cyclic clusters in liquid ethanol. J. Chem. Phys. 144 (2016) 154302.
- M.P. Balanay, C.M.G. Enopia, S.H. Lee, D.H. Kim. Theoretical design of triphenylamine-based derivatives with asymmetric D-D-π-A configuration for dye-sensitized solar cells. Spectrochim. Acta, Part A 140 (2015) 382.
- M.P. Balanay, D.H. Kim. Molecular engineering of donor-acceptor co-polymers for bulk heterojunction solar cells. Comput. Theor. Chem. 1055 (2015) 15.
- M.P. Balanay, D.H. Kim. Theoretical study on the correlations between dye-iodine interactions and open-circuit voltages in dyes containing furan and thiophene. Comput. Theor. Chem. 1029 (2014) 1.
For a complete list of publications please refer to
Spring 2024
- CHEM 431 – Computational Chemistry
- CHEM 511 – Theoretical Chemistry
- CHEM 731 – Design of Functional Materials
- CHEM 798 – Thesis Research
Fall 2023
- CHEM 471 – Environmental Chemistry
- CHEM 522 – Analytical Environmental Chemistry
- CHEM 722 – Advanced Environmental Chemistry
- CHEM 691 – Thesis Proposal
- CHEM 798 – Thesis Research
- CHEM 591 – Scientific Methods in Chemistry (team-taught course)
- CHEM 700 – Hot Topics in Chemistry (team-taught course)
Summer 2023
- CHEM 798 – Thesis Research
Spring 2023
- CHEM 431 – Computational Chemistry
- CHEM 511 – Theoretical Chemistry
- CHEM 731 – Design of Functional Materials
- CHEM 798 – Thesis Research
Fall 2022
- CHEM 400 – Chemistry Seminar
- CHEM 471 – Environmental Chemistry
- CHEM 522 – Analytical Environmental Chemistry
- CHEM 722 – Advanced Environmental Chemistry
- CHEM 691 – Thesis Proposal
- CHEM 798 – Thesis Research
Summer 2022
- CHEM 189c – Independent Study
Spring 2022
- CHEM 102 – General Chemistry II
- CHEM 431 – Computational Chemistry
- CHEM 511 – Theoretical Chemistry
Fall 2021
- CHEM 471 – Environmental Chemistry
- CHEM 522 – Analytical Environmental Chemistry
- CHEM 591 – Scientific Methods in Chemistry